Serie Homóloga de los Compuestos Orgánicos

Serie Homóloga de los Compuestos Orgánicos


Son aquellos compuestos orgánicos que están constituidos por el mismo grupo funcional, lo que conlleva a que tengan características, propiedades físicas y químicas similares. Una de las diferencias principales de las series homologas es la longitud de la cadena de carbonos.

Un ejemplo seria, los alcanos lineales ya que tienen el mismo grupo funcional y solo se diferencian por el metileno (CH2). Por lo tanto, los alcanos presentan una fórmula general para sus homólogos, la cual es CH3(CH2)nCH3 donde n es la cantidad de veces que se repite el grupo metileno.

Entonces vemos que el propano cuya fórmula es CH3CH2CH3 presentan un n=1, no obstante el pentano de fórmula CH3CH2CH2CH2CH3, tiene un n=3 y ambos son homólogos.

Otro ejemplo son los alcoholes, donde el grupo oxhidrilo (OH) es el grupo funcional principal, como se observa en los siguientes compuestos primarios:

CH3-CH2OH etanol

CH3– CH2– CH2– CH2-CH2-CH2OH 1-hexanol


Propiedades de las series homólogas
  • Presentan la misma fórmula general
  • Tienen un comportamiento químico similar
  • Las propiedades físicas como puntos de ebullición, estado físico y punto de fusión, aumentan a medida que incrementa su masa molar.
  • La masa molar es mayor a medida que en los miembros de la serie homóloga aumenta el número de carbonos.


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