Los alcoholes se caracterizan por presentar un grupo funcional hidroxilo (-OH), unido a un átomo de carbono, que a su vez hace parte de una cadena hidrocarbonada, alifática y saturada. Pueden considerarse como derivados del agua, a través de la sustitución de un hidrógeno por un grupo alquilo R-OH
Clasificación de los alcoholes
-
Según la posición del grupo hidroxilo:
Alcoholes primarios: Cuando el grupo hidroxilo está enlazado a un carbono primario.
Alcoholes secundarios: Cuando el grupo hidroxilo está enlazado a un carbono secundario.
Alcoholes terciarios: Cuando el grupo hidroxilo está enlazado a un carbono terciario.
-
Según el número de grupos hidroxilos:
Monovalentes o monoles: Son aquellos que presentan un solo grupo OH. Ejemplo: todos los señalados anteriormente.
Divalentes o glicoles: Son aquellos que presentan dos grupos OH.
Ejemplo:
Nombre IUPAC: Etanodiol
Nombre Común: Etilenglicol
Trivalente o glicerol: Son aquellos que presentan tres grupos OH.
Nombre IUPAC: Propanotriol
Nombre Común: Glicerina
*Nota* Es importante tener en cuenta que un mismo átomo de carbono no puede contener dos grupos hidroxilos y si llegara a suceder, la sustancia perdería inmediatamente una molécula de agua, convirtiéndose así en un aldehído o cetona.
Nomenclatura orgánica para alcoholes
-
Nomenclatura IUPAC.
Posición del grupo OH – Alcanol
Se enumera a partir de tres carbonos
-
Nomenclatura Común.
Alcohol alquílico
Esta nomenclatura se utiliza para alcoholes primarios, secundarios y terciarios. Para alcoholes más complejos se recomienda la nomenclatura IUPAC.
- Alquenoles
Posición del doble enlace – Alquen – Posición del grupo OH- ol
- Alquinoles
Posición del triple enlace – Alquin – Posición del grupo OH- ol
- Como radical: se nombra hidroxi al grupo -OH
Ejercicios
- CH3-OH
IUPAC: Metan-1-ol
Común: Alcohol metílico
- CH3-CH2-OH
IUPAC: Etan-1-ol
Común: Alcohol etílico
3.
IUPAC: propan-1-ol
Común: Alcohol n-propílico
*Se inicia enumerando desde el extremo donde se encuentre más cerca el grupo OH*
4.
IUPAC: propan-2-ol
Común: Alcohol isopropílico
5.
IUPAC: 5,5-dimetil-hexan-1-ol.
Común: Alcohol neooctílico
6.
IUPAC: 3,5-dimetil-heptan-4-ol
Común: no tiene nombre
7.
IUPAC: 4-Penten-2-ol
Común: no tiene nombre
8.
IUPAC: 4-pentin-1-ol
Común: no tiene nombre
9.
IUPAC: Ciclohexan-1-ol
Común: Alcohol ciclohexílico
10.
IUPAC: Ciclohex-2-en-1-ol
También es correcto:2-ciclohexen-1-ol
Común: Alcohol ciclohexenílico
Amigo en algunas parte coloca la nimenclatura IUPAC del 1979 y en otra los nombra como debe ser, es decir la nomenclatura de 1998
Hola amigo feliz tarde, está en lo correcto, modificaré los ejercicios que contengan la nomenclatura del 79.
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The essentials list: Tennis champ Coco Gauff shares her 7 everyday essentials
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After Coco Gauff won her first U.S. Open in September, plenty of sports commentators understandably credited her smashing forehand, big serve and amazing stamina. It turns out the 19-year-old also had a secret weapon in her arsenal.
“Before I walk on court for a match, I’m always listening to music,” Gauff says. “Usually something that pumps me up!” Her favorite song? Jaden Smith’s “Icon.”
As for the headphones playing her music? Ahead of the 2023 French Open in May, Gauff announced that she had partnered with audio equipment company Bose. “It was such an easy decision for me,” she says. “I listen to music every day, but especially in competition. I always have my headphones on because it puts me in the zone and allows me to focus.”
When she’s not in must-win playing mode, Gauff chills like most other 19-year-olds. She says she spends her off days going to the movies and watching Netflix. She also likes to explore the cities she travels to for tournaments and enjoys “trying the local cuisine.” And during her time back home in Delray Beach, Florida, she plays super-fan. “I love going to my brothers’ sporting events,” she says. “My youngest brother plays football, and my middle brother plays baseball.”
But overall, Gauff adds, “I give my best every day.”
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