Equilibrio Químico (Ejercicios Resueltos)

Equilibrio Químico (Ejercicios Resueltos)

El equilibrio químico es el estado de un sistema donde no se observan cambios en la concentración de los reactivos o productos, y que al transcurrir el tiempo, estas se mantienen constantes. 

Este proceso se da en las reacciones reversibles, donde la velocidad de las reacción de reactivos a productos es la misma que de productos a reactivos. 

Constante de equilibrio químico

La constante Kc para una reacción en equilibrio, es una fracción cuyo numerador es el producto de las concentraciones en mol/L de las sustancias del lado derecho y el denominador es el producto de las concentraciones en mol/L del lado izquierdo, cada concentración elevada a una potencia igual al coeficiente de la respectiva sustancia en la ecuación química balanceada.

La expresión matemática para Kc sería la siguiente:

Todas las especies químicas deben estar en estado gaseoso para participar en el equilibrio. En el caso de que alguno de los productos o reactantes estén en estado sólido o líquido, no se les considera en la expresión de equilibrio (Kc) debido a la poca variación que sufren durante el proceso.

Por ejemplo, se tiene la siguiente reacción:

El primer paso es observar si necesita ser balanceada y luego descartar las especies que estén en estado sólido o en estado líquido.

Para finalmente, escribir la expresión de la constante de equilibrio químico:

Ahora bien, se puede hallar el valor de Kc sabiendo que las especies involucradas presentan las siguientes concentraciones:

H2S = 5 mol/L

H2 = 1,5 mol/L

Sustituyendo en la constante anterior, nos queda:

Kc= 11,11


 

  • En un recipiente de 1 litro de capacidad se encuentran mezclados 10 moles de CO y 5 moles de H2O, sabiendo que la Kc es 8,25. Calcule la concentración en equilibrio de todas las especies involucradas en la reacción.

Primero se balancea la reacción si es necesario y luego se escribe la expresión de Kc para la reacción:

Luego se hallan las concentraciones en el equilibrio.

 

Ahora sustituimos los valores de las concentraciones en equilibrio en la constante de equilibrio anterior:

 

 

 

 

Se descarta el valor del volumen ya que para efecto de los cálculos matemáticos, es despreciable.

8,25. (50-15X +X) = X2

412,5 – 123,75 X + 8,25 X– X= 0

412, 5 – 123,75 X + 7,25 X  = 0

Se aplica la ecuación de segundo grado:

y queda que X1 = 12,53 y X2= 4,54. El valor que tomaremos para hallar las concentraciones en equilibrio es el de X2 ya que el valor de X1 es muy alto con respecto a las concentraciones iniciales.

Finalmente se hallan las concentraciones en el equilibrio:

H2 = CO2 = X = 4,54 mol ÷ 1 Litro = 4,54 mol/L

CO = 10 – X = 10- 4,54 ÷ 1 Litro =  5,46 mol/L

H2O = 5- X = 5- 4,54 ÷ 1 Litro = 0,46 mol/L

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    Multiple Payment Options. 4rabet app supports several payment methods, including popular options such as UPI, credit/debit cards, and e-wallets like Paytm, ensuring that users can deposit and withdraw funds conveniently.
    Customer Support. The app offers dedicated customer support through live chat, email, and phone, catering to users’ needs and resolving any issues that may arise.
    The 4rabet app has emerged as a popular choice among Indian sports bettors and casino enthusiasts, thanks to its extensive sports selection, user-friendly interface, and tailored features for the Indian market. By offering a safe and legal platform, competitive odds, and an array of bonuses and promotions, the app provides an engaging and rewarding experience for Indian users.

    Which of them are included in the line of games presented on the 4Rabet platform?
    content image
    Bonuses at 4rabet India
    One of the significant factors contributing to its popularity is the variety of enticing bonuses and promotions offered by the platform 4rabet. These bonuses not only enhance the overall gaming experience but also provide users with additional opportunities to maximize their winnings.

    New and existing users can benefit from a wide array of promotions available on 4rabet India, ranging from welcome bonuses to cashback offers and referral programs. These incentives encourage user engagement, loyalty, and retention, making the platform even more appealing to a broader audience. Below is a brief overview of some of the bonuses offered by 4rabet India:

    Welcome Bonus: New users can claim a generous welcome bonus on their first deposit, which typically offers a 100% to 200% match up to a specific amount (e.g., INR 20,000).
    Free Bets: 4rabet occasionally provides users with free bets, allowing them to place wagers without risking their own funds. These promotions are usually available during major sports events or tournaments.
    Reload Bonuses: Existing users can take advantage of periodic reload bonuses that offer a percentage match on subsequent deposits, encouraging continued engagement on the platform.
    Cashback Offers: 4rabet may provide cashback offers, allowing users to receive a percentage of their net losses back as bonus funds, incentivizing continued play and loyalty.
    Referral Program: Users can earn additional bonuses by referring friends to join the platform. When a referred friend signs up and makes their first deposit, both the referrer and the new user receive bonus funds.
    Seasonal and Event-based Promotions: 4rabet often runs time-limited promotions and offers related to specific sports events, festivals, or holidays, providing users with unique opportunities to boost their winnings or earn extra rewards.
    4raBet Betting on Sports
    At your service are available:

    Cricket (the main category with which 4rabet started their sportsbook)
    Soccer
    Tennis
    Basketball
    FIFA
    Ice hockey
    Table tennis
    Volleyball
    Handball
    Among more or less traditional sports, participants in the online betting platform 4Rabet have the opportunity to place bets on e-sports competitions as well, which include such disciplines as Dota 2, League of Legends, and Starcraft!

    Quality
    Of course, 4Rabet owes its origin to a team of developers from India and it was originally planned to become the first online betting platform for residents of India, but with the growing popularity of the project, 4Rabet has become truly world-famous, and now it can be confidently called a truly international project.

    A wide variety of cricket bets & other sports
    content image
    As we mentioned earlier, at the very beginning of its formation, the 4Rabet platform positioned itself mainly as an online betting platform for cricket betting – one of the most popular sports in India.

    I must say that Indians love cricket and all of its varieties.

    Indians loooove cricket!
    content image
    It’s no surprise that 4Rabet offers such a variety of bets on this beautiful and incredibly addicting sport that is beloved by many Indians.

    On the 4Rabet platform, you can place bets on regional matches as well as on matches in world championships and ranked cricket games.

    4Rabet Registration
    content image
    The registration process on the 4Rabet site is extremely simple.

    Visit the 4rabet website (www.4rabet.com) or download the app from Google Play Store or Apple App Store.
    Click on the «Sign Up» button.
    Fill in the registration form with your email address, password, and preferred currency (e.g., INR).
    Confirm your email address by clicking on the verification link sent to your inbox.
    Complete your profile by providing personal information such as your name, date of birth, and contact details.
    Verify your identity by submitting the required documents (e.g., ID card, passport, or driver’s license).
    Once verified, deposit funds into your account using your preferred payment method, and you’re ready to start betting.
    Technical Support on 4rabet
    content image
    4rabet review
    Technical support works around the clock and to communicate with technical support agents, you can either write an email (describing your problem in detail and indicating the subject in the title of the letter) or contact technical support directly on the site using the chat window for communication.

    Within a few minutes, a technical support employee will contact you in order to answer your questions.

    Given the growing popularity of the 4Rabet platform, many users are expected to have the following questions:
    Is 4Rabet a scam?

    Is 4Rabet legit?

    What are the ways to withdraw money from 4Rabet? What are the ways to deposit money on 4Rabet?

    Will there be problems with money withdrawing from the 4Rabet platform if my bet wins in the end?

    So, we hasten to assure you – we personally checked the functionality of the 4Rabet platform using our own deposit on the platform and tried to withdraw money.

    We did not have any problems with either depositing or withdrawing whatsoever – the money is credited to the card within a few minutes (in some individual cases – hours or maybe 2-3 days, in case there are some technical issues on the platform).

    The only condition for successful deposit/withdrawal of fiat funds from the platform is mandatory registration, which will not take you more than 5 minutes (either by email or by phone number).

    Money Depositing and Withdrawing
    Methods for depositing money into your account include:

    Visa (debit and credit cards)
    Mastercard (debit and credit cards)
    Skrill
    Neteller
    PhonePe
    Our Conclusion
    We checked the platform’s functionality, got acquainted with the numerous range of sports events presented on the platform, the variety of bet types and odds, the low commission of the platform, and came to the conclusion that the 4Rabet online betting platform is one of the fastest-growing, high-quality and, most importantly, reliable online betting platforms in the world today.

    4Rabet is Legal?
    We spent quite a lot of time on the platform in order to carefully weigh all the advantages and disadvantages of the service, the usability of the interface, and so on.

    content image
    In this case, it was not so easy to draw up a thorough examination, since earlier we reviewed exclusively cryptocurrency exchanges and aggregators, decentralized platforms, online brokerage platforms, and other projects related to blockchain technology and cryptocurrencies.

    However, in this respect, 4Rabet is transparent as glass. They are officially certified to carry out such activities, they have all the necessary registrations, so customers do not have to worry about the safety of their accounts.

    In addition, no history of hacks, scams, and other problems on the platform has arisen before, therefore, in this regard, we can confidently declare that the 4Rabet platform is a reliable and proven online betting platform.

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    Not long out of college, Shelton was relatively unknown on the circuit having only been pro for the past six months. But armed with a lethal serve and the fearlessness of youth, things were about to change – fast.

    “I feel like it went from nobody knowing me to a lot of people knowing me kind of overnight,” Shelton tells CNN Sport. “It felt really quick.”

    Skip ahead 12 months and the 21-year-old American is in Australia preparing to play in his sixth grand slam and second at Melbourne Park.

    At this point in his young career, Shelton’s results have been excellent: he reached the quarterfinals of last year’s Australian Open and went a step further at the US Open, eventually losing to Novak Djokovic in a fiery semifinal. Several weeks after that, he won his first ATP Tour title in Japan.

    It figures, then, that Shelton enters his second full season as a professional tennis player with weighty expectations.

    “He could cut his ranking in half,” tennis coach and broadcaster Brad Gilbert recently told CNN, “and I think he’s going to be the first American potentially to win a slam since Andy Roddick.”