Átomos Isoelectrónicos. Ejercicios Resueltos

Átomos Isoelectrónicos. Ejercicios Resueltos

Los átomos isoelectrónicos son aquellos que presentan igual cantidad de electrones en su capa de valencia, al realizarse su configuración electrónica. También se le llama isoelectronicidad. Por ejemplo, el anión flúor, el neón y el catión sodio son isolectrónicos entre ellos. Sigue leyendo y te explicaré porqué estas especies presentan igual configuración electrónica. 

Para saber si existe isoelectronicidad entre dichas especies, se debe realizar la configuración electrónica de cada una de ellas. Además debes recordar que los aniones son especies negativas que ganan electrones y los cationes son especies positivas que pierden electrones. 

Anión flúor ( F¯ ): El flúor en su estado neutro posee un Z o número atómico de 9. No obstante, se dice que forma un anión cuando este gana un electrón, quedando ahora su numero atómico: Z = 9 + 1 = 10 electrones.

Su configuración electrónica es la siguiente: 1s2 2s2 2p6 

Neón (Ne): Este elemento presenta un Z= 10 (10 electrones), como está en su estado neutro, no hay perdida ni ganancias de electrones.

Quedando su configuración electrónica:  1s2 2s2 2p6 

Catión Sodio (Na+): El sodio en su estado neutro presenta un Z o número atómico de 11. Sin embargo, este forma un catión cuando pierde un electrón, quedando su número atómico, de la siguiente manera: Z= 11-1 = 10 electrones

Su configuración electrónica es la siguiente:  1s2 2s2 2p6 

Como te habrás dado cuenta, todas las especies presentan 8 electrones en su capa de valencia (la capa más externa). Por lo tanto, se dice que estas son isoelectrónicas.

 

Ejercicios
  • Escriba las configuraciones electrónicas de las especies siguientes: N3-  Mg2+  Cl–  KAr y además indique las entidades que son isoelectrónicas. 

N3-  Nitrógeno Z= 7 + 3 (gana 3 electrones) = 10; Configuración electrónica: 1s2 2s2 2p6

Mg2+  Magnesio Z = 12 – 2 (pierde 2 electrones) = 10; Configuración electrónica: 1s2 2s2 2p6

Cl–  Cloro Z= 17 + 1 (gana 1 electrón) = 18 electrones; Configuración electrónica: 1s2 2s2 2p6 3s2 3p6

KPotasio Z= 19 – 1 ( pierde 1 electrón) = 18 electrones; Configuración electrónica: 1s2 2s2 2p6 3s2 3p6

Ar Argón Z= 18; Configuración electrónica: 1s2 2s2 2p6 3s2 3p6

Resultado: El N3-  y Mg2+ son especies isoelectrónicas entre ellas, debido a que presentan 10 electrones en su distribución electrónica. Por su parte, las especies Cl, K+, Ar son isoelectrónicas entre ellas ya que todas poseen 18 electrones en su configuración electrónica.


 

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