Las mezclas azeotrópicas o simplemente azeótropos son aquellas mezclas líquidas conformadas por dos o más compuestos químicos que tienen comportamientos similares, y en sus propiedades se observa como si estuviese constituida por un solo componente. Este aspecto se evidencia cuando hierves la mezcla, mostrándose que su fase de vapor tendrá la misma composición que su fase líquida.
Algunos ejemplos de mezclas azeotrópicas tenemos:
HClO4 al 28,4 % + H2O. La mezcla hierve a 203 °C
H2SO4 al 98,3 % + H2O. La mezcla hierve a 336 °C.
HNO3 al 68,4 % + H2O. La mezcla hierve a 122 °C.
CLASIFICACIÓN DE LAS MEZCLAS AZEOTRÓPICAS
Clasificación según su punto de ebullición:
Azeótropos positivos: Son aquellas mezclas azeotrópicas que presentan ebullición mínima según las desviaciones positivas de la Ley de Raoult.
Azeótropos negativos: Son aquellas mezclas azeotrópicas que presentan ebullición positiva según las desviaciones negativas de la Ley de Raoult.
Clasificación según la miscibilidad entre componentes
Azeótropos homogéneos: En este tipo de mezcla azeotrópica, los componentes que la conforman, son miscibles entre ellos.
Azeótropos heterogéneos: En este tipo de mezcla azeotrópica, los componentes que la conforman, son inmiscibles entre ellos, originándose varias fases líquidas, según el tipo de mezcla.
Clasificación según la cantidad de componentes
Mezcla azeotrópica binaria: Es aquella mezcla formada por dos componentes.
Mezclas azeotrópicas ternarias: Formada por tres componentes.
Mezclas azeotrópicas cuaternarias: Está formada por 4 componentes.
Y así sucesivamente…
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