Las hidroxilaminas son compuestos orgánicos considerados derivados de la hidroxilamina u oxiamoníaco cuya fórmula es NH2OH, el cual proviene de sustituir un átomo de hidrógeno del amoníaco por un hidroxilo. El reemplazo de átomos de hidrógeno en la molécula de la hidroxilamina H2N-OH, da lugar a la fórmula general: R-NHOH.
Estos compuestos se nombran como derivados de la hidroxilamina, es decir, se debe emplear el sufijo hidroxilamina. Se utilizan los localizadores 1 y 2 para señalar sustituciones, es decir, N y N’.
NOMENCLATURA PARA LAS HIDROXILAMINAS
Tanto para el sistema IUPAC como para el sistema Común, las hidroxilaminas se nombran colocando primero el nombre de los radicales, seguido de la palabra hidroxilamina. La numeración de los carbonos se inicia desde el carbono que está conectado al grupo funcional –NHOH.
EJERCICIOS
IUPAC: 5-metil-1-hexilhidroxilamina
Común: isoheptil-hidroxilamina
IUPAC: N-fenilhidroxilamina
Común: No posee
IUPAC: N,N-dimetilhidroxilamina
Común: No posee
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