Se entiende por composición centesimal de una sustancia, los valores en términos de porcentaje de cada uno de los elementos que la constituyen. Se obtiene por análisis gravimétrico y conociendo las masas atómicas de los compuestos puede determinarse su fórmula mínima o molecular.
Ejercicios
-
Conocida la fórmula del cloruro de calcio (CaCl2), determinar el % de calcio y de cloro en dicha sustancia.
Paso 1. Se debe determinar la masa molecular del CaCl2:
Masa atómica del calcio = 40
Masa atómica del cloro = 35,5
Ca + 2Cl → CaCl2
40 + 2. (35,5) = 111g/mol
Paso 2. Ahora se debe hallar el % de calcio:
Si en 111 g de CaCl2 → 40 g de Ca
En 100 g → X
X = 36,1%
Paso 3. Determinar el % de cloro de igual manera que en el paso anterior:
Si en 111 g de CaCl2 → 71 g de Ca
En 100 g → X
X = 63,9%
Por lo tanto, en el cloruro de calcio, hay 36,1% de calcio y 63,9% de cloro = 100%
2. Determinar los porcentajes de potasio, cloro y oxígeno en el clorato de potasio (KClO3).
Paso 1. Se debe determinar la masa molecular del KClO3
Masa atómica del potasio = 39
Masa atómica del cloro = 35,5
Masa atómica del oxígeno= 16
K + Cl + O → KClO3
39 + 35,5 + 3.(16) = 122,5 g/mol
Paso 2. Ahora se debe hallar el % de K. Cl y O:
Si en 122,5 g de KClO3 → 39 g de K
En 100 g → X
X = 31,84% de Potasio
Si en 122,5 g de KClO3 → 35,5 g de Cl
En 100 g → X
X = 28,98% de Cloro
Si en 122,5 g de KClO3 → 48 g de O
En 100 g → X
X = 39,18% Oxígeno
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